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The design, synthesis and characterization of polynuclear materials for applications for catalysis
Includes abstract.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
| Published: |
Department of Chemistry
2015
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| _version_ | 1867613498672939008 |
|---|---|
| access_status_str | Open Access |
| author | Makhubela, Banothile Charity Events |
| author2 | Smith, Gregory S |
| author_browse | Makhubela, Banothile Charity Events Smith, Gregory S |
| author_facet | Smith, Gregory S Makhubela, Banothile Charity Events |
| author_sort | Makhubela, Banothile Charity Events |
| collection | Thesis |
| description | Includes abstract. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/11505 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:37:06.658Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2015 |
| publishDateRange | 2015 |
| publishDateSort | 2015 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/11505 The design, synthesis and characterization of polynuclear materials for applications for catalysis Makhubela, Banothile Charity Events Smith, Gregory S Jardine, Anwar Chemistry Includes abstract. Includes bibliographical references. The synthesis and characterization of new chitosan- and 6-deoxy-6-amino chitosan-supported ligands is discussed. This was achieved via the reaction of either 2-pyridinecarboxaldehyde or 2-(diphenylphosphino)benzaldehyde with the accessible amino groups of chitosan to afford chitosan-supported Schiff base ligands (2.1-2.4) bearing iminopyridyl and iminophosphine functionalities on the surface. Complexation reactions with [PdCl2(COD)] and [RhCl(CO)2]2 gave the corresponding chitosan-supported complexes (2.5-2.8) and (2.13-2.14). These metal-containing materials and their precursors were isolated as air and moisture stable solids which proved insoluble in common organic solvents and have been characterized analytically and spectroscopically... 2015-01-05T18:57:44Z 2015-01-05T18:57:44Z 2012 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/11505 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Makhubela, Banothile Charity Events The design, synthesis and characterization of polynuclear materials for applications for catalysis |
| thesis_degree_str | Doctoral |
| title | The design, synthesis and characterization of polynuclear materials for applications for catalysis |
| title_full | The design, synthesis and characterization of polynuclear materials for applications for catalysis |
| title_fullStr | The design, synthesis and characterization of polynuclear materials for applications for catalysis |
| title_full_unstemmed | The design, synthesis and characterization of polynuclear materials for applications for catalysis |
| title_short | The design, synthesis and characterization of polynuclear materials for applications for catalysis |
| title_sort | design synthesis and characterization of polynuclear materials for applications for catalysis |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/11505 |
| work_keys_str_mv | AT makhubelabanothilecharityevents thedesignsynthesisandcharacterizationofpolynuclearmaterialsforapplicationsforcatalysis AT makhubelabanothilecharityevents designsynthesisandcharacterizationofpolynuclearmaterialsforapplicationsforcatalysis |