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Includes bibliographical references.
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| Format: | Thesis |
| Language: | English |
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Department of Chemical Engineering
2015
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| _version_ | 1867611347733184512 |
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| access_status_str | Open Access |
| author | Viljoen, Carl |
| author2 | Möller, Klaus |
| author_browse | Möller, Klaus Viljoen, Carl |
| author_facet | Möller, Klaus Viljoen, Carl |
| author_sort | Viljoen, Carl |
| collection | Thesis |
| description | Includes bibliographical references. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/12791 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2015 |
| publishDateRange | 2015 |
| publishDateSort | 2015 |
| publisher | Department of Chemical Engineering |
| publisherStr | Department of Chemical Engineering |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/12791 Assessment of disparate strategies for octane prediction Viljoen, Carl Möller, Klaus Yates, Andrew Chemical Engineering Includes bibliographical references. Octane quality is a key factor in determining the profitability in a modern refinery. The final commercial product is defined by the combined blend of various gasoline component streams which are produced from different units within the refinery. The accurate prediction of the octane numbers of these blends enables the economic optimization of the production process. Currently, empirical octane models are used exclusively for this purpose. Octane is a measure of the spontaneous autoignition propensity of a fuel-air mixture and it is quantified using a specific engine-based test method. This research project was founded on the premise that an improved octane prediction model could be harvested from building blocks that included a fundamental understanding of autoignition, appropriate choices of autoignition models and an engine model. This objective was pursued in this work by investigating detailed and reduced kinetic mechanisms for the oxidation of selected fuel molecules using various modeling techniques. Empirical octane models and semi-chemical models of autoignition were also investigated. All of these methodologies were assessed as possible strategies towards octane prediction. In this study it was observed that both detailed and highly reduced kinetic models could describe the oxidation behaviour of pure fuel components and predict their subsequent ignition delays. 2015-05-13T14:17:35Z 2015-05-13T14:17:35Z 2009 Doctoral Thesis Doctoral PhD http://hdl.handle.net/11427/12791 eng application/pdf Department of Chemical Engineering Faculty of Engineering and the Built Environment University of Cape Town |
| spellingShingle | Chemical Engineering Viljoen, Carl Assessment of disparate strategies for octane prediction |
| thesis_degree_str | Doctoral |
| title | Assessment of disparate strategies for octane prediction |
| title_full | Assessment of disparate strategies for octane prediction |
| title_fullStr | Assessment of disparate strategies for octane prediction |
| title_full_unstemmed | Assessment of disparate strategies for octane prediction |
| title_short | Assessment of disparate strategies for octane prediction |
| title_sort | assessment of disparate strategies for octane prediction |
| topic | Chemical Engineering |
| url | http://hdl.handle.net/11427/12791 |
| work_keys_str_mv | AT viljoencarl assessmentofdisparatestrategiesforoctaneprediction |