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Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte

This research project investigated the selective removal of Co²⁺ and Ni²⁺ from a Co-Ni-Mn system through sulphide precipitation. The Co²⁺ and Ni²⁺ ions have adverse effects on the purity of the manganese product, thus, have to be removed via precipitation in a purification st...

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Main Author: Dube, Vuyiswa
Other Authors: Lewis, Alison Emslie
Format: Thesis
Language:English
Published: Department of Chemical Engineering 2015
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access_status_str Open Access
author Dube, Vuyiswa
author2 Lewis, Alison Emslie
author_browse Dube, Vuyiswa
Lewis, Alison Emslie
author_facet Lewis, Alison Emslie
Dube, Vuyiswa
author_sort Dube, Vuyiswa
collection Thesis
description This research project investigated the selective removal of Co²⁺ and Ni²⁺ from a Co-Ni-Mn system through sulphide precipitation. The Co²⁺ and Ni²⁺ ions have adverse effects on the purity of the manganese product, thus, have to be removed via precipitation in a purification step. The main objective of this research was to understand the influence of local supersaturation on the purification process. This was important for controlling such a process to achieve residual ion concentrations of 0.3 ppm and 1.0 ppm for Co²⁺ and Ni²⁺ ions respectively, with minimum loss of the Mn²⁺ ions.
format Thesis
id oai:open.uct.ac.za:11427/13710
institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:33:26.520Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2015
publishDateRange 2015
publishDateSort 2015
publisher Department of Chemical Engineering
publisherStr Department of Chemical Engineering
record_format dspace
source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/13710 Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte Dube, Vuyiswa Lewis, Alison Emslie Pascual, Marcos Rodriguez Chemical Engineering This research project investigated the selective removal of Co²⁺ and Ni²⁺ from a Co-Ni-Mn system through sulphide precipitation. The Co²⁺ and Ni²⁺ ions have adverse effects on the purity of the manganese product, thus, have to be removed via precipitation in a purification step. The main objective of this research was to understand the influence of local supersaturation on the purification process. This was important for controlling such a process to achieve residual ion concentrations of 0.3 ppm and 1.0 ppm for Co²⁺ and Ni²⁺ ions respectively, with minimum loss of the Mn²⁺ ions. 2015-08-12T04:04:26Z 2015-08-12T04:04:26Z 2015 Master Thesis Masters MSc (Eng) http://hdl.handle.net/11427/13710 eng application/pdf Department of Chemical Engineering Faculty of Engineering and the Built Environment University of Cape Town
spellingShingle Chemical Engineering
Dube, Vuyiswa
Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte
thesis_degree_str Master's
title Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte
title_full Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte
title_fullStr Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte
title_full_unstemmed Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte
title_short Study of selective removal of CoS and NiS during purification of MnSO₄ electrolyte
title_sort study of selective removal of cos and nis during purification of mnso 8324 electrolyte
topic Chemical Engineering
url http://hdl.handle.net/11427/13710
work_keys_str_mv AT dubevuyiswa studyofselectiveremovalofcosandnisduringpurificationofmnso8324electrolyte