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Synthesis of delta-1(9)-octalinols and their analogues
Includes bibliographical references.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2016
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| _version_ | 1867613253846171648 |
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| access_status_str | Open Access |
| author | Lupuwana, Lincoln L |
| author2 | Elsworth, J F |
| author_browse | Elsworth, J F Lupuwana, Lincoln L |
| author_facet | Elsworth, J F Lupuwana, Lincoln L |
| author_sort | Lupuwana, Lincoln L |
| collection | Thesis |
| description | Includes bibliographical references. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/16406 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:33:12.104Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2016 |
| publishDateRange | 2016 |
| publishDateSort | 2016 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/16406 Synthesis of delta-1(9)-octalinols and their analogues Lupuwana, Lincoln L Elsworth, J F Organic Chemistry Includes bibliographical references. This project was initiated by the observation that a natural glyeoside of a triterpene, which incorporated the allylic alcoholic moiety 1 gave the novel ketone diene 2 when it was subjected to acetolysis. A number of octahydronaphthalinols (1, R=H) Δ 1 ( 9) octalinols), ' were prepared by reduction of the α, β unsaturated octalones obtained from cyclohexanones condensed with α, β -unsaturated ketones. These octalinols were characterised as their acetates (1, R=Ac). The attempts to convert these to the desired ketone dienes 2 by reaction with mixtures of acetic anhydride-acetic acid-boron trifluoride proved unsuccessful. Two model compounds derived from hecogenin and incorporating the octalinol residue 1 were also prepared in the hope that the analogous ketone 2 might be obtained. This reaction, too, was unsuccessful. 2016-01-15T14:18:48Z 2016-01-15T14:18:48Z 1986 Master Thesis Masters MSc http://hdl.handle.net/11427/16406 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Organic Chemistry Lupuwana, Lincoln L Synthesis of delta-1(9)-octalinols and their analogues |
| thesis_degree_str | Master's |
| title | Synthesis of delta-1(9)-octalinols and their analogues |
| title_full | Synthesis of delta-1(9)-octalinols and their analogues |
| title_fullStr | Synthesis of delta-1(9)-octalinols and their analogues |
| title_full_unstemmed | Synthesis of delta-1(9)-octalinols and their analogues |
| title_short | Synthesis of delta-1(9)-octalinols and their analogues |
| title_sort | synthesis of delta 1 9 octalinols and their analogues |
| topic | Organic Chemistry |
| url | http://hdl.handle.net/11427/16406 |
| work_keys_str_mv | AT lupuwanalincolnl synthesisofdelta19octalinolsandtheiranalogues |