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An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste

The manufacture, transport, use and disposal of organic chemicals may result in the release of significant quantities of organic substances into soil, from which they are subject to possible transport into underlying groundwater. Many of these organic chemicals are potentially toxic (Wilson et al.,...

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Main Author: Huntsman, Philippa Rose
Other Authors: Fey, Martin V
Format: Thesis
Language:English
Published: Department of Geological Sciences 2016
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access_status_str Open Access
author Huntsman, Philippa Rose
author2 Fey, Martin V
author_browse Fey, Martin V
Huntsman, Philippa Rose
author_facet Fey, Martin V
Huntsman, Philippa Rose
author_sort Huntsman, Philippa Rose
collection Thesis
description The manufacture, transport, use and disposal of organic chemicals may result in the release of significant quantities of organic substances into soil, from which they are subject to possible transport into underlying groundwater. Many of these organic chemicals are potentially toxic (Wilson et al., 1981). Information is required concerning the chemical and physical behaviour of organic chemicals in the soil environment in order to implement measures that will protect groundwater but also permit reasonable usage of soil for waste containment. This study deals with the interactions of a smectitic clay soil of the Rensburg form and two petrochemical wastes, which were sampled from storage dams, adjacent to a petrochemical plant at Secunda, South Africa. There is growing interest at the plant in utilizing soil for cost-effective waste containment and treatment. The objectives of this study were twofold: firstly, to determine the permeability of the Rensburg soil with respect to the two waste liquids (BPlO- aqueous and phenolic, and BP2- non-aqueous); and, secondly, to investigate the sorptive capacity of the clay fraction of the soil for two common groundwater contaminants, benzene and phenol, in the context of the potential for using treated clays for decontaminating BP10 and other organic wastes. The Rensburg soil was compared with a commercial bentonite for containing and treating petrochemical waste.
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institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:33:15.376Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2016
publishDateRange 2016
publishDateSort 2016
publisher Department of Geological Sciences
publisherStr Department of Geological Sciences
record_format dspace
source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/19708 An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste Huntsman, Philippa Rose Fey, Martin V Willis, James Environmental Geochemistry The manufacture, transport, use and disposal of organic chemicals may result in the release of significant quantities of organic substances into soil, from which they are subject to possible transport into underlying groundwater. Many of these organic chemicals are potentially toxic (Wilson et al., 1981). Information is required concerning the chemical and physical behaviour of organic chemicals in the soil environment in order to implement measures that will protect groundwater but also permit reasonable usage of soil for waste containment. This study deals with the interactions of a smectitic clay soil of the Rensburg form and two petrochemical wastes, which were sampled from storage dams, adjacent to a petrochemical plant at Secunda, South Africa. There is growing interest at the plant in utilizing soil for cost-effective waste containment and treatment. The objectives of this study were twofold: firstly, to determine the permeability of the Rensburg soil with respect to the two waste liquids (BPlO- aqueous and phenolic, and BP2- non-aqueous); and, secondly, to investigate the sorptive capacity of the clay fraction of the soil for two common groundwater contaminants, benzene and phenol, in the context of the potential for using treated clays for decontaminating BP10 and other organic wastes. The Rensburg soil was compared with a commercial bentonite for containing and treating petrochemical waste. 2016-05-18T07:12:46Z 2016-05-18T07:12:46Z 1996 Master Thesis Masters MSc http://hdl.handle.net/11427/19708 eng application/pdf Department of Geological Sciences Faculty of Science University of Cape Town
spellingShingle Environmental Geochemistry
Huntsman, Philippa Rose
An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste
thesis_degree_str Master's
title An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste
title_full An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste
title_fullStr An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste
title_full_unstemmed An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste
title_short An investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste
title_sort investigation into the use of smectitic clay soil for the containment and treatment of petrochemical waste
topic Environmental Geochemistry
url http://hdl.handle.net/11427/19708
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