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Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity
Bibliography: p. 125-129.
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| Main Author: | |
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2016
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| _version_ | 1867614394068762624 |
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| access_status_str | Open Access |
| author | Pelling, Simon |
| author2 | Moss, John R |
| author_browse | Moss, John R Pelling, Simon |
| author_facet | Moss, John R Pelling, Simon |
| author_sort | Pelling, Simon |
| collection | Thesis |
| description | Bibliography: p. 125-129. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/21426 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:51:20.574Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2016 |
| publishDateRange | 2016 |
| publishDateSort | 2016 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/21426 Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity Pelling, Simon Moss, John R Bibliography: p. 125-129. Transition metal methoxymethyl and chloromethyl complexes may be versatile starting materials for the synthesis of several types of new complexes, including hydroxymethyl and carbene complexes, respectively [LₙMCH₂OH] and [LₙMCH₂]⁺ (M=transition metal, L=ligands). Hydroxymethyl and carbene transition metal complexes are models of catalytic intermediates in the Fischer-Tropsch reaction. We have synthesized the new chloromethyl complexes [Ru(Cp)(CO)₂CH₂CI], [Re(CO)₅CH₂CI], and cis-[Mn(CO)₄(PPh₃)CH₂CI], and the new methoxymethyl The existence of rotational isomerism in the complexes [Ru(Cp)(CO)₂CH₂ocH₃] and the previously reported [Fe(Cp)(CO)₂CH₂OCH₃],⁴⁸ is proposed on the basis of infrared data. Mass spectra of several methoxymethyl and chloromethyl transition metal complexes have been recorded. 2016-08-22T12:26:03Z 2016-08-22T12:26:03Z 1981 Master Thesis Masters MSc http://hdl.handle.net/11427/21426 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Pelling, Simon Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity |
| thesis_degree_str | Master's |
| title | Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity |
| title_full | Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity |
| title_fullStr | Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity |
| title_full_unstemmed | Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity |
| title_short | Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity |
| title_sort | chloromethyl and methoxymethyl transition metal complexes an investigation into their synthesis and reactivity |
| url | http://hdl.handle.net/11427/21426 |
| work_keys_str_mv | AT pellingsimon chloromethylandmethoxymethyltransitionmetalcomplexesaninvestigationintotheirsynthesisandreactivity |