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The total synthesis of aristolindiquinone
Bibliography: pages 97-99.
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2016
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| _version_ | 1867613340438626304 |
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| access_status_str | Open Access |
| author | Botha, Marc Edgar |
| author2 | Giles, Robin G F |
| author_browse | Botha, Marc Edgar Giles, Robin G F |
| author_facet | Giles, Robin G F Botha, Marc Edgar |
| author_sort | Botha, Marc Edgar |
| collection | Thesis |
| description | Bibliography: pages 97-99. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/22134 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:34:33.896Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2016 |
| publishDateRange | 2016 |
| publishDateSort | 2016 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/22134 The total synthesis of aristolindiquinone Botha, Marc Edgar Giles, Robin G F Chemistry Bibliography: pages 97-99. Aristolindiquinone (1), a novel natural compound possibly: possessing anti-fertility activity, was synthesized via two independent routes. First, a Stobbe reaction unambiguously gave the naphthalene nucleus with the required substitution pattern (3,8-dioxygenated-2,5-dimethyl naphthalene), starting from 2-hydroxy-5-methylbenzaldehyde (31). Second, a general synthesis, of substituted C-5 oxygenated- 1,4-naphthoquinones is applied to the synthesis of (1). The critical step in the synthesis is the reaction of the novel Diels-Alder partners, dienophile (90), synthesized from 2,6-dihydroxytoluene (56), and diene (109). 2016-10-14T06:27:15Z 2016-10-14T06:27:15Z 1986 Master Thesis Masters MSc http://hdl.handle.net/11427/22134 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Botha, Marc Edgar The total synthesis of aristolindiquinone |
| thesis_degree_str | Master's |
| title | The total synthesis of aristolindiquinone |
| title_full | The total synthesis of aristolindiquinone |
| title_fullStr | The total synthesis of aristolindiquinone |
| title_full_unstemmed | The total synthesis of aristolindiquinone |
| title_short | The total synthesis of aristolindiquinone |
| title_sort | total synthesis of aristolindiquinone |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/22134 |
| work_keys_str_mv | AT bothamarcedgar thetotalsynthesisofaristolindiquinone AT bothamarcedgar totalsynthesisofaristolindiquinone |