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Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran

Although life on Earth evolved in the Archean, complex hard bodied animals only emerged in shallow marine environments during the late Ediacaran (~550 Ma). The trigger for the appearance of these hard-bodied animals is still debated but it was probably related to ecological and/or environmental chan...

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Main Author: Mtonda, Mcdonald Takondwa
Other Authors: Tostevin, Rosalie
Format: Thesis
Language:English
Published: Department of Geological Sciences 2023
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access_status_str Open Access
author Mtonda, Mcdonald Takondwa
author2 Tostevin, Rosalie
author_browse Mtonda, Mcdonald Takondwa
Tostevin, Rosalie
author_facet Tostevin, Rosalie
Mtonda, Mcdonald Takondwa
author_sort Mtonda, Mcdonald Takondwa
collection Thesis
description Although life on Earth evolved in the Archean, complex hard bodied animals only emerged in shallow marine environments during the late Ediacaran (~550 Ma). The trigger for the appearance of these hard-bodied animals is still debated but it was probably related to ecological and/or environmental change. Continental weathering fluxes into the oceans can influence redox conditions and seawater chemistry and can be tracked using the strontium isotope ratio of seawater, which can be faithfully captured by carbonate minerals. However, analysis of strontium isotopes in ancient carbonates can be complicated by diagenetic alteration. To ensure that the 87Sr/86Sr ratios generated in this study were reflective of primary seawater signals, a sequential leaching procedure, first proposed by Bailey et al., (2000), was tested on Ediacaran bulk rock carbonate samples. The successful implementation of the sequential digestion technique was verified through careful examination of samples for diagenetic alteration using petrography, trace element ratios and  18O. The sequential digestion technique was then applied to a high-resolution stratigraphic transect through terminal Ediacaran carbonate rocks from the Nama Group, collected in South Africa and Namibia. The isotopic signature of these rocks is consistent with other terminal Ediacaran age rocks, with typically slightly positive  13C and relatively high 87Sr/86Sr ratios (~0.7085). Correlation with other Ediacaran basins reveals a drop in 87Sr/86Sr from ~0.7090 to ~0.7085 ca. 550 Ma. The drop was likely due to location of palaeocontinents compounded by palaeoclimatic cooling during the terminal Ediacaran. These changes provide important context for a critical period in metazoan evolution and may have influenced the cost-benefit ratio of producing hard body parts.
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institution University of Cape Town (South Africa)
language eng
last_indexed 2026-06-10T12:31:54.917Z
license_str Not specified — see source repository
provenance_str_mv Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository
publishDate 2023
publishDateRange 2023
publishDateSort 2023
publisher Department of Geological Sciences
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source_str UCTD — University of Cape Town Open Access Repository
spelling oai:open.uct.ac.za:11427/38083 Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran Mtonda, Mcdonald Takondwa Tostevin, Rosalie Geological Sciences Although life on Earth evolved in the Archean, complex hard bodied animals only emerged in shallow marine environments during the late Ediacaran (~550 Ma). The trigger for the appearance of these hard-bodied animals is still debated but it was probably related to ecological and/or environmental change. Continental weathering fluxes into the oceans can influence redox conditions and seawater chemistry and can be tracked using the strontium isotope ratio of seawater, which can be faithfully captured by carbonate minerals. However, analysis of strontium isotopes in ancient carbonates can be complicated by diagenetic alteration. To ensure that the 87Sr/86Sr ratios generated in this study were reflective of primary seawater signals, a sequential leaching procedure, first proposed by Bailey et al., (2000), was tested on Ediacaran bulk rock carbonate samples. The successful implementation of the sequential digestion technique was verified through careful examination of samples for diagenetic alteration using petrography, trace element ratios and  18O. The sequential digestion technique was then applied to a high-resolution stratigraphic transect through terminal Ediacaran carbonate rocks from the Nama Group, collected in South Africa and Namibia. The isotopic signature of these rocks is consistent with other terminal Ediacaran age rocks, with typically slightly positive  13C and relatively high 87Sr/86Sr ratios (~0.7085). Correlation with other Ediacaran basins reveals a drop in 87Sr/86Sr from ~0.7090 to ~0.7085 ca. 550 Ma. The drop was likely due to location of palaeocontinents compounded by palaeoclimatic cooling during the terminal Ediacaran. These changes provide important context for a critical period in metazoan evolution and may have influenced the cost-benefit ratio of producing hard body parts. 2023-07-12T09:31:32Z 2023-07-12T09:31:32Z 2023 2023-07-12T09:30:43Z Master Thesis Masters MSc http://hdl.handle.net/11427/38083 eng application/pdf Department of Geological Sciences Faculty of Science
spellingShingle Geological Sciences
Mtonda, Mcdonald Takondwa
Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran
thesis_degree_str Master's
title Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran
title_full Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran
title_fullStr Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran
title_full_unstemmed Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran
title_short Using high resolution Sr isotope data from the Nama Group, South Africa, to constrain global stratigraphic relationships and continental weathering rates in the terminal Ediacaran
title_sort using high resolution sr isotope data from the nama group south africa to constrain global stratigraphic relationships and continental weathering rates in the terminal ediacaran
topic Geological Sciences
url http://hdl.handle.net/11427/38083
work_keys_str_mv AT mtondamcdonaldtakondwa usinghighresolutionsrisotopedatafromthenamagroupsouthafricatoconstrainglobalstratigraphicrelationshipsandcontinentalweatheringratesintheterminalediacaran