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Synthetic studies towards an organometallic rotaxane
The synthesis of interlocking molecules such as rotaxanes and catenanes is a branch of supramolecular chemistry of particular current interest. The aim of this work was to assess the viability of the synthesis of an organometallic rotaxane in which the transition metal is covalently bonded to a carb...
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| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2023
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| _version_ | 1867613835659051008 |
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| access_status_str | Open Access |
| author | Mare, Jacques Simon Fife |
| author2 | Moss |
| author_browse | Mare, Jacques Simon Fife Moss |
| author_facet | Moss Mare, Jacques Simon Fife |
| author_sort | Mare, Jacques Simon Fife |
| collection | Thesis |
| description | The synthesis of interlocking molecules such as rotaxanes and catenanes is a branch of supramolecular chemistry of particular current interest. The aim of this work was to assess the viability of the synthesis of an organometallic rotaxane in which the transition metal is covalently bonded to a carbon atom of an alkyl group. The formation of a rotaxane using the host cyclophane, cyclobis (paraquat-pphenylene), formed by a template effect, has been investigated using our chiral organometallic polyether. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/38703 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:42:28.033Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2023 |
| publishDateRange | 2023 |
| publishDateSort | 2023 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/38703 Synthetic studies towards an organometallic rotaxane Mare, Jacques Simon Fife Moss Chemistry The synthesis of interlocking molecules such as rotaxanes and catenanes is a branch of supramolecular chemistry of particular current interest. The aim of this work was to assess the viability of the synthesis of an organometallic rotaxane in which the transition metal is covalently bonded to a carbon atom of an alkyl group. The formation of a rotaxane using the host cyclophane, cyclobis (paraquat-pphenylene), formed by a template effect, has been investigated using our chiral organometallic polyether. 2023-09-15T14:23:52Z 2023-09-15T14:23:52Z 1996 2023-09-15T14:23:32Z Master Thesis Masters MSc http://hdl.handle.net/11427/38703 eng application/pdf Department of Chemistry Faculty of Science |
| spellingShingle | Chemistry Mare, Jacques Simon Fife Synthetic studies towards an organometallic rotaxane |
| thesis_degree_str | Master's |
| title | Synthetic studies towards an organometallic rotaxane |
| title_full | Synthetic studies towards an organometallic rotaxane |
| title_fullStr | Synthetic studies towards an organometallic rotaxane |
| title_full_unstemmed | Synthetic studies towards an organometallic rotaxane |
| title_short | Synthetic studies towards an organometallic rotaxane |
| title_sort | synthetic studies towards an organometallic rotaxane |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/38703 |
| work_keys_str_mv | AT marejacquessimonfife syntheticstudiestowardsanorganometallicrotaxane |