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Mixed-ligand diruthenium complexes: theoretical modelling and interpretation of electronic absorption spectra

The speciation and improved solubility of Ru₂(μ-O₂CCH₃)₃(μ-2-Fap)X complexes, where 2-Fap is 2-(2-fluoroanilino)pyridinate, and X represents Cl, Br or I, are influenced by the axial ligand (X) lability and solvent coordination at the axial site. These complexes have Ru(II) and Ru(III) metal centers...

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Bibliographic Details
Main Author: Mutomb, Jean-Luc
Other Authors: Ngubane, Siyabonga
Format: Thesis
Language:English
English
Published: Department of Chemistry 2026
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