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Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes
Includes abstract.
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| Other Authors: | |
| Format: | Thesis |
| Language: | English |
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Department of Chemistry
2014
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| _version_ | 1867613222614335488 |
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| access_status_str | Open Access |
| author | Chellan, Prinessa |
| author2 | Smith, Gregory S |
| author_browse | Chellan, Prinessa Smith, Gregory S |
| author_facet | Smith, Gregory S Chellan, Prinessa |
| author_sort | Chellan, Prinessa |
| collection | Thesis |
| description | Includes abstract. |
| format | Thesis |
| id | oai:open.uct.ac.za:11427/6297 |
| institution | University of Cape Town (South Africa) |
| language | eng |
| last_indexed | 2026-06-10T12:32:42.829Z |
| license_str | Not specified — see source repository |
| provenance_str_mv | Harvested via OAI-PMH from UCTD — University of Cape Town Open Access Repository |
| publishDate | 2014 |
| publishDateRange | 2014 |
| publishDateSort | 2014 |
| publisher | Department of Chemistry |
| publisherStr | Department of Chemistry |
| record_format | dspace |
| source_str | UCTD — University of Cape Town Open Access Repository |
| spelling | oai:open.uct.ac.za:11427/6297 Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes Chellan, Prinessa Smith, Gregory S Chibale, Kelly Chemistry Includes abstract. Includes bibliographical references. Nine monothiosemicarbazone ligands were prepared by Schiff-base condensation reactions of thiosemicarbazide and the appropriate aryl aldehyde or ketone. These compounds were isolated as air- and moisture- stable solids and were characterized using NMR and IR spectroscopies, as well as mass spectrometry and elemental analysis in the case of ligand 3-terl.-butyl-2-hydroxy-benzaldehyde thiosemicarbazone, which is a new compound. Four of these ligands were reacted with precursors of type Pd(L)2CI2 yielding eight tridentate thiosemicarbazone Pd(II) complexes with general formula [Pd( 3-0,N,Sthiosemicarbazone)(L)] (L = PPh3 or 4-picoline). Six of these complexes are new compounds and were fully characterized using NMR and IR spectroscopies, mass spectrometry and elemental analysis. In addition, the solid state structures of three complexes were elucidated using single crystal X-ray diffraction methods. 2014-08-13T14:26:00Z 2014-08-13T14:26:00Z 2009 Master Thesis Masters MSc http://hdl.handle.net/11427/6297 eng application/pdf Department of Chemistry Faculty of Science University of Cape Town |
| spellingShingle | Chemistry Chellan, Prinessa Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes |
| thesis_degree_str | Master's |
| title | Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes |
| title_full | Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes |
| title_fullStr | Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes |
| title_full_unstemmed | Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes |
| title_short | Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes |
| title_sort | synthesis characterization biological and catalytic studies of tridentate monothiosemicarbazone palladium ii complexes |
| topic | Chemistry |
| url | http://hdl.handle.net/11427/6297 |
| work_keys_str_mv | AT chellanprinessa synthesischaracterizationbiologicalandcatalyticstudiesoftridentatemonothiosemicarbazonepalladiumiicomplexes |